Abstract (from http://journals.ametsoc.org/doi/abs/10.1175/JAMC-D-15-0276.1): Remotely sensed land skin temperature (LST) is increasingly being used to improve gridded interpolations of near-surface air temperature. The appeal of LST as a spatial predictor of air temperature rests in the fact that it is an observation available at spatial resolutions fine enough to capture topoclimatic and biophysical variations. However, it remains unclear if LST improves air temperature interpolations over what can already be obtained with simpler terrain-based predictor variables. Here, the relationship between LST and air temperature is evaluated across the conterminous United States (CONUS). It is found that there are significant differences in the ability of daytime and nighttime observations of LST to improve air temperature interpolations. Daytime LST mainly indicates finescale biophysical variation and is generally a poorer predictor of maximum air temperature than simple linear models based on elevation, longitude, and latitude. Moderate improvements to maximum air temperature interpolations are thus limited to specific mountainous areas in winter, to coastal areas, and to semiarid and arid regions where daytime LST likely captures variations in evaporative cooling and aridity. In contrast, nighttime LST represents important topoclimatic variation throughout the mountainous western CONUS and significantly improves nighttime minimum air temperature interpolations. In regions of more homogenous terrain, nighttime LST also captures biophysical patterns related to land cover. Both daytime and nighttime LST display large spatial and seasonal variability in their ability to improve air temperature interpolations beyond simpler approaches.